Modeling with First-Order Equations
A rate law is a differential equation. Each first-order model starts from one governing principle: conservation of mass for a mixing tank, proportional change for interest and radioactive decay, Newton's law of cooling, a force balance for a body falling against drag, and Kirchhoff's law for a series circuit.
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Differential equations pervade the sciences because a statement about a rate of change is a statement about a derivative. Newton's cooling, radioactive decay, and population growth are each an assertion that some quantity changes at a rate proportional to something measurable, and each becomes a first-order equation the moment it is written in symbols. Modeling proceeds in three steps.1
- Construct. Translate the governing physical principle into an equation relating a quantity and its derivative, stating clearly what law is assumed.
- Analyze. Solve the equation, or extract qualitative information about its solutions when a closed form is out of reach.
- Compare. Interpret the solution in context and test it against observation; a model is validated by its predictions, not its derivation.
The equations are approximate by construction: insect populations do not grow without bound, heat transfer depends on more than temperature difference, and no tank is perfectly stirred. Knowing where a model breaks down is part of using it.
Mixing
A tank holds gallons of water with pounds of salt dissolved at time . Brine at concentration lb/gal flows in at gal/min, and the well-stirred mixture drains at the same rate. The governing principle is conservation of salt: the rate of change of salt equals the rate in minus the rate out.
Salt enters at lb/min and leaves at lb/min, so
This is linear. In standard form , the integrating factor is , and the general solution is . Applying ,
The limiting amount is lb, obtainable without solving by setting : eventually the tank contents match the inflow concentration, lb. The exponential records how the initial charge relaxes to that steady state.
The same tank model, with a time-varying inflow concentration, produces an oscillating steady state. If chemical enters a pond at concentration , the content settles into a fixed oscillation about a constant level once the exponential transient decays — the same transient-plus-steady-state split seen for linear equations.
Exponential growth and decay
When a quantity changes at a rate proportional to its current size, , the solution is : growth for , decay for . Three standard applications share this skeleton.
- Compound interest. A balance earning return continuously satisfies , so . With continuous deposits at rate the equation becomes , solved by .
- Radioactive decay. An amount of a radioisotope obeys , so . The half-life satisfies , giving . Radiocarbon dating inverts this: measuring recovers the elapsed time .
- Newton's cooling. A body at temperature in surroundings at cools at a rate proportional to the difference, , so approaches ambient exponentially.
Continuous compounding is the limit of discrete compounding. Compounding times a year gives , and recovers the continuous model; the frequency of compounding barely matters in practice.
Falling body with drag
A body of mass falls under gravity against a resistive force proportional to its speed. Taking velocity positive downward, Newton's second law gives
with the drag coefficient. In standard form , this is linear with integrating factor , and
The exponential decays, so every solution approaches the terminal velocity, the speed at which drag exactly balances gravity and . The same value falls out of the equation by setting the right side to zero without integrating.
If instead the field varies with altitude, as for a body projected far from the earth, the equation is nonlinear. Writing the gravitational force as and using to trade time for altitude gives the separable equation .
Series circuits
An RL circuit with resistance , inductance , and applied voltage carries a current . Kirchhoff's voltage law sets the applied voltage equal to the sum of the voltage drops — across the resistor and across the inductor:2
With constant the integrating factor is and
The current climbs toward the steady value set by Ohm's law, with the inductor delaying the approach; the time constant fixes the pace. The RC circuit, with charge obeying , has the identical linear form and the same transient-plus-steady structure. This shared equation is the basis for the mechanical–electrical analogy developed for second-order systems.
Summary
Each model begins with one governing law and ends as a first-order equation whose long-time behavior is the physically meaningful output.
| Model | Governing principle | Equation | Long-time behavior |
|---|---|---|---|
| Mixing tank | conservation of mass | ||
| Interest / growth | rate amount | exponential growth | |
| Radioactive decay | rate amount | exponential decay | |
| Cooling | rate difference | ||
| Falling body (drag) | force balance | ||
| RL circuit | Kirchhoff's voltage law |
In every case the steady state is obtained by setting the derivative to zero, and the transient records the approach from the initial condition. A nonlinear rate law, such as logistic growth or a threshold population, produces richer behavior from the same setup.
Footnotes
- Boyce, Elementary Differential Equations, §2.3 — Modeling with First-Order Differential Equations: the three-step modeling process and the mixing, compound-interest, and escape-velocity examples worked here. ↩
- Simmons, Differential Equations, Ch. 2 §13 — Simple Electric Circuits: Kirchhoff's law applied to the series RL and RC circuits. The growth, decay, cooling, and falling-body models follow Ch. 1 §4–§5. ↩
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