Phase Transitions/Mean-Field Theory and Spontaneous Symmetry Breaking

Lesson 11.31,109 words

Mean-Field Theory and Spontaneous Symmetry Breaking

Mean-field theory replaces the neighbors of each spin by their average, turning the interacting Ising model into a single spin in a self-consistent field. The resulting equation m = tanh(beta J z m + beta h) has only the zero solution above a critical temperature and gains a nonzero root below it, giving spontaneous magnetization and a mean-field critical temperature k T_c = J z.

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The Ising model resists exact solution above one dimension because each spin is coupled to its neighbors, which are coupled to theirs, and the sum over configurations does not factorize. Mean-field theory cuts the coupling by a single approximation: replace the fluctuating neighbors of a given spin by their average value, so that each spin responds not to its actual environment but to a uniform effective field set self-consistently by the average magnetization. The interacting many-spin problem collapses to one spin in an external field, solvable in closed form. The price is that fluctuations are discarded, and the theory is quantitatively right only where fluctuations are weak — in high dimension.

The Weiss mean field

Write each spin as its average plus a fluctuation, , where is the magnetization per spin and . A nearest-neighbor product becomes

The mean-field approximation drops the product of two fluctuations , the term that carries the correlations. Each bond then contributes . On a lattice where every site has nearest neighbors there are bonds, and the Hamiltonian reduces to a sum of single-spin terms,

Every spin now sees the same effective field

the applied field augmented by the Weiss molecular field from the averaged neighbors. The spins are decoupled, so the partition function factorizes into copies of a single two-state system, and the average of one spin in field is . Demanding that this average equal the that produced the field closes the loop.

Spontaneous magnetization and the critical temperature

Set the applied field to zero and study . The line and the curve always intersect at the origin, the disordered solution . Whether they intersect anywhere else is fixed by the slope of the tanh at the origin, which is .

  • If , the tanh is shallower than the diagonal everywhere and the only solution is : the system is disordered.
  • If , the tanh starts above the diagonal and bends back to cross it at a nonzero : two ordered solutions appear, and becomes unstable.

The borderline defines the mean-field critical temperature

The graphical solution of ; below the tanh (steep curve) is steeper than the diagonal at the origin and crosses it at , while above (shallow curve) the only crossing is at the origin.

Near the transition the ordered root is small, and expanding gives . With , the leading balance is

The spontaneous magnetization turns on continuously at with the mean-field exponent , the value the exact two-dimensional result contradicts. As the tanh saturates and : every spin aligns.

The mean-field spontaneous magnetization rises continuously from zero at as and saturates toward full alignment as ; above it is identically zero.

The Bragg-Williams free energy

The self-consistency equation is the stationarity condition of a free energy in the trial variable . The mean-field energy per spin is , and the entropy per spin of a state with magnetization is fixed by counting configurations with fraction up:

The Bragg-Williams free energy per spin is , and reproduces . Expanding the entropy for small , , collects the free energy into a polynomial in the order parameter,

The coefficient of changes sign at . Above it is positive and has a single minimum at . Below it is negative, turns into a local maximum, and the quartic term stabilizes two symmetric minima at . The Landau expansion of the next lesson is this polynomial, here obtained from a microscopic model.

The Bragg-Williams free energy at zero field; above a single well at , below a double well with symmetric minima at separated by a maximum at the origin.

Spontaneous symmetry breaking

The zero-field Hamiltonian is invariant under flipping every spin, , which sends . Above the equilibrium state shares that symmetry: is invariant. Below the two equilibrium states and each violate the symmetry, and the system must occupy one of them. Which one it picks is not determined by the Hamiltonian; an infinitesimal field, or a chance fluctuation frozen in as the system cools, selects the branch. The symmetry of the laws is not shared by the state. This is spontaneous symmetry breaking, and it is the mechanism of every ordered phase: the ferromagnet picks a direction, the crystal picks a lattice origin, the superfluid picks a phase.

In the field-temperature plane the ordered region is bordered by a line of first-order transitions. For the segment is a coexistence line: crossing it flips the magnetization discontinuously between and , a first-order jump with the field as control variable. The line ends at the critical point , beyond which no discontinuity remains and the magnetization is a smooth function of through zero.

The mean-field phase boundary in the field-temperature plane; the segment for is a first-order line across which the magnetization jumps, terminating at the critical point .

The two minima are separated by a free-energy barrier that scales with system size, so in the thermodynamic limit the system cannot tunnel between them. This is why the symmetry is broken in practice and not merely on paper: a macroscopic magnet stays magnetized in one direction for astronomically long times. A finite system, by contrast, samples both minima and averages to , another statement that a sharp transition lives only in the thermodynamic limit.

Range of validity

Mean-field theory neglects the fluctuation term , so it is trustworthy only when fluctuations of the order parameter are small compared with its mean. Each spin feels neighbors; the more neighbors, the better an average represents them, so the approximation improves as (hence the dimension ) grows. Two limits make this precise.

  • Upper critical dimension. Above the fluctuation corrections to mean-field theory are finite and do not alter the exponents: mean-field exponents are exact for . The infinite-range model (every spin coupled to every other) is mean-field exact in any dimension.
  • Ginzburg criterion. The self-consistency of neglecting fluctuations requires that the mean-square fluctuation of the order parameter within a correlation volume be small next to . Evaluating this near gives a reduced-temperature window inside which fluctuations dominate and mean-field theory fails. The window closes () for and is finite for .1

Below four dimensions — including the physically important cases and — mean-field exponents are wrong near , and the exact Ising value in two dimensions is the sharpest demonstration. Getting the exponents right requires summing the fluctuations, the achievement of the renormalization group. Mean-field theory nonetheless captures the qualitative structure correctly: a transition at a definite , a continuously vanishing order parameter, symmetry breaking, and a double-well free energy. Those features survive; only the numbers shift.

Summary

  • Mean-field theory replaces each spin's neighbors by their average, dropping the fluctuation product ; the effective field decouples the spins into single-spin problems.
  • The self-consistency equation has only above and gains ordered roots below, with and (exponent ).
  • The Bragg-Williams free energy is single-welled above and double-welled below, the Landau form derived microscopically.
  • Selecting one of the two minima breaks the up-down symmetry spontaneously; a size-scaling barrier locks the choice in the thermodynamic limit.
  • Neglecting fluctuations makes the theory exact for (upper critical dimension) and the infinite-range model, but wrong exponents for ; the Ginzburg criterion sets the temperature window where fluctuations take over.

Footnotes

  1. Kardar (Fields), §3.3, and Pathria & Beale, §12.6. The Ginzburg criterion compares the fluctuation integral over a correlation volume with ; the two scale with the same power of only at .

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