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Quantum Mechanics

Quantum mechanics trades the certainty of a trajectory for the bookkeeping of an amplitude: a complex-valued wave whose squared magnitude gives the probability of what you will find. A particle no longer has a position until you look — it has a distribution.

FIG_002
sourcescreen
Single quanta land as points, yet their tally builds an interference pattern — |ψ₁ + ψ₂|².

The double slit is the whole subject in miniature. Fire electrons one at a time and each strikes the screen as a single dot, particle-like; let thousands accumulate and the dots organize into fringes, wave-like. The superposition of two paths interferes, and asking which slit it took destroys the pattern.

The Schrödinger equation is the law of motion for the amplitude. Given a potential, it evolves the wavefunction deterministically in time — the randomness lives only in what a measurement extracts, not in how the state itself develops.

FIG_003
E0E_0
E1E_1
E2E_2
E3E_3
V(x)
Confine a particle and its energy quantizes: standing-wave eigenstates on discrete levels.

Confinement forces quantization. Bound in a well, only the standing waves that fit survive, and their energies become a discrete ladder. This is why atoms have sharp spectral lines and why the world at small scales is granular rather than continuous.

Observables — position, momentum, energy, spin — become operators, and the only values a measurement can return are their eigenvalues. When two operators fail to commute, as position and momentum do, no state can have a definite value of both: that is the uncertainty principle.

FIG_001
xvgΨ(x,t)
A matter wavepacket: a localized bump of probability drifting and spreading, built from a band of momenta around ħk.
FIG_004
0|0\rangle
1|1\rangle
ψ
A qubit as a point on the Bloch sphere, precessing about the z-axis under its Hamiltonian.

The simplest quantum system is a two-level one — a spin, a qubit — and its entire state space is the surface of a sphere. Angular momentum and spin, quantized and intrinsically non-classical, run through everything from magnetic resonance to the structure of the periodic table.

FIG_005
ψ|\psi\rangle
measure
0|0\rangle
1|1\rangle
P(outcome)
Measurement collapses a superposition onto one eigenstate, with the Born-rule probabilities.

Measurement is where the theory meets the world. A superposition carries several outcomes at once, each weighted by an amplitude; observing it collapses the state onto a single eigenstate, at random, with probability given by the Born rule.

Because exact solutions are rare, the working physicist leans on approximation — perturbation theory, the variational method, and the algebraic tricks of the harmonic oscillator — to make real atoms, molecules, and solids tractable.

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